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Q.

For a reaction, activation energy Ea=0  and the rate constant at 200 K is 1.6×106s-1. The rate constant at 400 K will be [Given that gas constant, R = 8.314 J K1 mol1]

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a

1.6×106s1

b

3.2×106s1

c

3.2×104s1

d

1.6×103s1

answer is C.

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Detailed Solution

From Arrhenius equation

logk400k200=Ea2.303RT2T1T1T2

 Since, given that Ea=0 logk400k200=0=log 1k400k200=1  So, k400=k200  So rate constant at 400K=1.6×106s1

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