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Q.

For a reaction A(g)  products,    the following data are available.

Initial pressure of A,pA/ Torr        429               273                     150

Half-life period, t1/2/S                       350               550                      1001

The order of the reaction is

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a

0

b

1

c

2

d

3

answer is C.

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Detailed Solution

For zero-order reaction t1/2[A]0 For first-order reaction t1/2= constant 

 For second-order reaction  t1/21/[A]0 For third-order reaction t1/21/[A]02

For the given data, t1/2[A]0 is constant:

(429 Torr) (350 s) = 150 150 Torr s          (273 Torr) (550 s) = 150 150 Torr s

(150 Torr) (1001 s) = 150 150 Torr s 

Thus, the reaction is second order

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