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Q.

For a reaction :

CH3COCH3+Br2H+CH3COCH2Br+H++Br

following data was obtained. From the data, identify the correct statement(s)

[Acetone]Br2H+[Rate of Reaction]
0.150.25 M 0.025 M6×104M sec1
0.150.50 M0.025 M6×104M sec1
0.150.25 M 0.050 M12×104M sec1
0.20.25 M 0.025 M8×104M sec1

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a

The overall order of the reaction is 2nd order.

b

Order of reaction with respect Br2 will be 1.

c

During the reaction, where H+  does not change it will follow first order kinetics.

d

When [ Acetone ]Br2 then reaction will proceed with variable rate for most of the reaction.

answer is A, B.

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Detailed Solution

Given reaction is,

CH3COCH3+Br2H+CH3COCH2Br+H++Br

The overall order of this reaction is 2nd order.

The rate law,

r=kBr20H+l[ Acetone ]1

While the reaction process, when H+  ion does not change, then it will follow first order kinetics.

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