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Q.

For a reaction the activation energy is zero. What is the value of rate constant at 300 K.
[Given k280 K=1.6×106 s-1;R=8.314Jmol-1 K-1 ]

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a

2.08×10-2

b

6.93×10-2

c

1.6×106

d

2.08×10-3

answer is C.

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Detailed Solution

Given T1=280 K,k1=1.6×106 s-1,k2=?,Ea=0, T2=300 K.
By Arrhenius equation,

logk1k1=Ea2.303RT2-T1 T2 T1 As,Ea=0 or k2k1=1 or k2=k1 Thus, the rate constant at300Kis1.6×106s1

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