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Q.

For a reaction 12A2B, the rate of disappearance of A is related to the rate of appearance ofB by the expression 

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a

d[A]/dt=(1/2)d[B]/dt

b

d[A]/dt=(1/4)d[B]/dt

c

d[A]/dt=d[B]/dt

d

d[A]/dt=4d[B]/dt

answer is C.

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Detailed Solution

For the reaction 12A2B, rate of disappearance of A is related to rate of appearance of B by the expression:

1VAd[A]dt=1VBd[B]dt  i.e.  1(1/2)d[A]dt=12d[B]dtHence, d[A]dt=14d[B]dt.

Hence, option C is correct.

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For a reaction 12A→2B, the rate of disappearance of A is related to the rate of appearance ofB by the expression