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Q.

For a reaction 2X(g)3Y(g)+2Z(g) the following data is obtained

Time (min)Px (mm of Hg) (Partial pressure of X)
0800
100400
200200

Find order (n) with respect to X, rate constant (k) of the reaction, time taken (in min.) for 75% completion t3/4 and find the total pressure when partial pressure of X, Px =700 mm of Hg. Report value of (PTotal×n×t3/4)1000  

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answer is 950.

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Detailed Solution

Clearly, t1/2 is independent of initial conc.

So, order must be 1st

t1/2=100 min, t3/4=200 min

2X(g)         3Y(g)    +2Z(g)

800x=700     3x2          x

PT=800+32×100

PT =950

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