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Q.

For a reaction A2(g)+2B2(g)2AB2, ΔrH=100kJmol1  and  ΔrS=250.0JK1mol1. The reaction will be spontaneous

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a

provided T=400 K

b

providedT>400 K

c

providedT<400 K

d

providedT>500 K

answer is C.

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Detailed Solution

Since ΔrG=ΔrHTΔrS<0 ,we have   ΔrHTΔrS>0  or  ΔrH>TΔΓS or T<ΔrH/ΔrS=100×103Jmol1/250JK1mol1=400 K.

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For a reaction A2(g)+2B2(g)⟶2AB2, ΔrH∘=−100kJmol−1  and  ΔrS∘=−250.0JK−1mol−1. The reaction will be spontaneous