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Q.

For a reaction A+BC+15D, kinetics is 5 determined by analysis of partial pressure of gases at different instants. Calculate the value of"a + b + c".

P mm of Hg t = 0t = 30 min t = 60 min 
PA2010a
PB10000Not applicable Not applicable 
PC0Not applicable 15
PD0bNot applicable 

where a = PA after t = 60 min b = PD after t = 30 min c = order of the reaction with respect to A.

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answer is 8.

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Detailed Solution

   At=0 20+B100C-+15D-

rA=k[A]; k=ln230

PAa=5;PDb=105=2;c=1

a+b+c=8

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