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Q.

For a reaction, A+BProducts, the rate is first order with respect to A and second order with respect to B. If 1.0 mole each of A and B are introduced into a 1 litre vessel and the initial rate were 1.0×102 mol litre1 sec1. The rate (in mol litre1 sec1) when half of the reactants have been used 

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a

1.25×103

b

1.2×102

c

2.5×104

d

1.25×10-5

answer is A.

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Detailed Solution

order w.r.t. A = 1

order w.r.t. B = 2

r=K[A]×[B]2

when A and B are consumed 50%, 

r'=K×[A2]×[B2]2=r×18=(1.0×102)×18=1.25×103

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