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Q.

For a reaction ΔH:(+3kJ)ΔS=(+10J/K) beyond which

temperature this reaction will be spontaneous 

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a

300 K 

b

200 K

c

273 K

d

373 K

answer is D.

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Detailed Solution

ΔG=ΔHTΔS For the spontaneous reaction the  G must be negative.  

ΔH=3KJ=+3000JΔS=+10J/K If T=300KΔG=3000300×10=0 If T=200KΔG=3000200×10=1000J If T=273KΔG=3000273×10=270J If T=373KΔG=3000373×10=730J

Hence, beyond 373 temperature the reaction will be spontaneous. 

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