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Q.

For a reversible reaction (first order in both directions)

Ak2k1B

k1and k2 are the rate constant

If equilibrium constant (K) is greater than unity, then:

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a

activation energy for the forward direction Eafis greater than activation energy for backward reaction Eab·

b

addition of a catalyst will increase both k1 and k2 by same factor

c

rate of forward reaction is always greater than rate of backward reaction.

d

amount of product at equilibrium is greater than the amount of reactant.

answer is A, B, D.

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Detailed Solution

The given reaction is reversible.

Activation energy for the forward direction Eafis equal to the activation energy for the backward reaction Eab·

Eaf=Eab

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