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Q.

For a reversible reaction Kp<Kc, for this reaction at equilibrium, increase of pressure favours

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a

neither forward reaction nor backward reaction

b

the forward reaction

c

the backward reaction

d

both forward and backward reaction equally

answer is C.

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Detailed Solution

Given KP <  KC

We know KP = KC (RT)Δn

given  

\large \frac{{{K_P}}}{{{K_C}}} < 1

only when Δng is negative.

 

Δng = np (g) - nR (g)

\large \because \Delta n_g

is negative

np (g) < nR (g)

 

From left to right i.e. forward reaction involves  decrease  in volume.

According to Le-Chatlier's principle reactions involving decrease in volume are favoured at high pressure.

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