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Q.

For a saturated solution of AgCl at 25°C, specific conductance is 3.55×106ohm1cm1 and that of water used for preparing the solution is 1.60×106ohm1cm1. If λAgCl=150ohm1cm2eq1, the Ksp of AgCl is 0.17×10xM2. The value of x is:
 

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answer is 9.

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Detailed Solution

Specific conductivity of pure AgCl = specific conductivity of saturated solution of AgCl- specific conductivity of H2O(l)
 

k=3.55×106 ohm1cm11.60×106 ohm1cm1=1.95×106 ohm1cm1

For saturated solution of sparingly soluble salt,

λV=λ and solubility = normality

λV=λ=1000×ks

c=1000×kλAgCl=1000×1.95×106150=1.31×105 M

Now,
KspAgCl=s2=1.31×1052=0.1716×109

X=9

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