Q.

For a unidirectional first order decomposition:

X(g) Y(g)+2Z(g)

Pure X(g) is taken in an evacuated flask at t = 0. After 10 seconds, a pin-hole is made in the flask and the gaseous mixture is allowed to effuse out into a vacuum. Analysis of the initial effused mixture reveals that moles of Z(g) were double the moles of X(g). If molar masses of X, Y and Z are 16, 8 and 4 respectively, rate constant for the decomposition of X is _________  sec1.

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answer is 0.04.

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