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Q.

For a unielectronic species, compare the energy of the following orbitals (represented by S)

S1=a spherically symmetrical orbital having two spherical nodes

S2=an orbital which is double-dumb bell and has no radial nodes

S3=an orbital with orbital angular momentum zero and three radial nodes

S4=an orbital having one planar and one radial node

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a

S1=S2=S4<S3

b

S1=S2=S3=S4

c

S1<S2<S3<S4

d

S1>S2>S3>S4

answer is B.

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Detailed Solution

S13sS23dS34sS43p

For unielectronic species energy depends only on ‘n’ 

S1=S2=S4<S3

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