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Q.

For a d4 metal ion in an octahedral field, the correct electronic configuration is:

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a

eg2t2g2when  Δ0<P

b

t2g3eg1when  Δ0>P

c

t2g3eg1when  Δ0<P

d

t2g4eg0when  Δ0<P

answer is A.

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Detailed Solution

When <P, the electrons will remain unpaired in t2g and eg orbitals because energy gap between the orbitals is small. This lead to the formation of a high spin complex. Hence, electronic arrangement becomes t2g3eg1.

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