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Q.

For an acid catalysed hydrolysis of an ester which of the following options regarding initial rate of reaction is correct?

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a

Rate of reaction will be same if 0.05 M HCl is taken or 0.05 M H2SO4 is taken.

b

There will be no effect of concentration of [H+] on rate of reaction

c

Rate of reaction will be faster when 1 M HCl is taken as compared to when 1 M CH3 COOH is taken.

d

The reaction proceeds following third order kinetics.

answer is C.

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Detailed Solution

r=kH+,[ester]= k' [ester];

k' value depends on  [H+].

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