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Q.

For an ideal binary liquid solution with pAo>pBo, xA and yA represent the mole fraction of A in liquid phase and vapor phase, respectively, whereas xB and yB represent the mole fraction of B in liquid phase and vapor phase, respectively. Therefore, which of the following relations is correct?

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a

xAxB>yAyB

b

xA=yA

c

xAxB<yAyB

d

xA>yA

answer is C.

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Detailed Solution

P'A=PA0xA=Psol×yA

P'B=PB0xB=Psol×yB

yAyB=pA0pB0×xAxB  (Since pA0>pB0

yAyB>xAxB

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For an ideal binary liquid solution with pAo>pBo, xA and yA represent the mole fraction of A in liquid phase and vapor phase, respectively, whereas xB and yB represent the mole fraction of B in liquid phase and vapor phase, respectively. Therefore, which of the following relations is correct?