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Q.

For an ionic micelle-forming surfactant near its critical micelle concentration (CMC), which of the following graphs rightly show the variation of mentioned properties with concentration of the surfactant

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a

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b

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c

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d

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answer is A, C.

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Detailed Solution

A concentration approaches concentration molar conductivity decreases steeply, surface tension keeps on decreasing and reaches a constant value, osmotic pressure keeps on increasing and reaches a steady value, detergency keeps on increasing and reaches the highest value.

C=CMC,(d3F/dCt3)=0

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