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Q.

For complete combustion of methanol CH3OHl+32O2gCO2g+2H2Ol The amount of heat produced as measured by bomb calorimeter is 726 kJ mol-1 at 27ºC. The enthalpy of combustion  at constant pressure for the reaction is xkJmol1, where x is _______(nearest integer) (Given : R=8.3JK1mol1)

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a

727      

b

345       

c

276    

d

715

answer is A.

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Detailed Solution

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CH3OHl+32O2gCO2g+2H2Ol

At 270CΔn=11.5=0.5

ΔH=ΔU+ΔnRT

=726+0.5300×8.3×103=7261.24

=727.24  kJ

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For complete combustion of methanol CH3OHl+32O2g→CO2g+2H2Ol The amount of heat produced as measured by bomb calorimeter is 726 kJ mol-1 at 27ºC. The enthalpy of combustion  at constant pressure for the reaction is −x kJ mol−1, where x is _______(nearest integer) (Given : R=8.3 JK−1mol−1)