Q.

For complete combustion of methanol

CH3OH(l)+32O2( g)CO2( g)+2H2O(l)

the amount of heat produced as measured by bomb calorimeter is 726 kJ mol-1 at 27°C. The enthalpy of combustion for the reaction is -x kJ mol-1, where x is ___________. (Nearest integer)

(Given : R=8.3JK-1 mol-1 )

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answer is 727.

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Detailed Solution

ΔU=-726KJ/mol Δng=1-32=-12 ΔH=ΔU+ΔngRT =-726-12×8.3×3001000 =-727.245

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