Q.

For complex ion/compound formation reactions
 (I) Co3+(aq)+EDTA4P
 (II) Ni2+(aq)+dmg (excess) NH4OHQ
 (III) Zn2+(aq)+ gly (excess) R
 (IV) Pt4+(aq)+ en (excess) S
Which of the following complex ion/compound does not exhibit optical activity ?

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a

S

b

R

c

Q

d

P

answer is B.

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Detailed Solution

Ni2+(aq) with DMG (dimethylglyoxime) form square plaaar complex which is obtically inactive. While [Co(EDTA)],Zn(gly)22+ and Pt(en)34+ are optically active as they do not have P.O.S.

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