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Q.

For dichromate dianion. Which of the following property is incorrect?

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a

The hybridization of chromium in Cr2O72 is sp3

b

Two CrO42 tetrahedrons are joined through oxygen

c

OCrO bond angle is less than that of CrOCr bond angle

d

Terminal CrO bonds are shorter than bridge CrO  bond lengths

answer is C.

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Detailed Solution

Due to resonance the terminal Cr-O bonds are get double bond character and becomes shorter than bridge bonds. In the formation of dichromate dianion two tetrahedral CrO42 ions condense through oxygen atom. The O-Cr-O bond angle is less since the bond pair electrons move towards more electronegative oxygen. The hybridization of chromium in the formation of CrO42  or   Cr2O72 is  d3s

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