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Q.

For electron gain enthalpies of the elements denoted as ΔegH, the incorrect option is: 

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a

ΔegH(I)<ΔegH(At)

b

ΔegH(Cl)<ΔegH(F)

c

ΔegH(Se)<ΔegH(S)

d

ΔegH(Te)<ΔegH(Po)

answer is A.

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Detailed Solution

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In 16th group elements, when an electron is added to an isolated gaseous sulphur atom more heat is liberated. So sulphur has lowest electron gain enthalpy than remaining elements in the group.
ΔHeg(S)=200 kJ.mol1ΔHeg(Se)=195 kJ.mol1

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