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Q.

For how long, a current of 1.5 amperes has to be passed through the electrolyte in order to deposit 1.5 g of Al, when the electrode reaction is

Al3++3eAl (round off the answer to two digits after the decimal)

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answer is 2.

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Detailed Solution

Reaction: Al3+1 mol+3e3 mol-Al1 mol=27 g

Charge on 3 moles  of electrons = 3 x 96500 coulombs

Total charge to deposit 27g Al = 3 x 96500 C

 Charge to deposit 1.5 g Al=3×96500×1.527=16083.3 C

To Calculate time (t). Current = 1.5 ampere; time  (t)=?

No. of coulombs = ampere x time (in seconds)

                           =1.5 × t.C

1.5 t = 16083.3

t=16083.31.5  Or  16083.31.5×60×60=2.9782.98 hours

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