Q.

For 'invert sugar', the correct statement(s) is/are) : [Given specific rotations of (+}·sucrose (+)-maltose, L-(-)-glucose and L-(+)-fructose in aqueous solution are +66°, +140°, -52° and +92° respectively.]

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a

'invert sugar' is prepared by acid catalyzed hydrolysis of maltose

b

'invert sugar' is an equimolar mixture of D-(+)-glucose and D~(-).fructose

c

specific rotation of 'invert sugar' is -20°

d

on reaction with Br2 water, 'invert sugar' forms saccharic acid as one of the products

answer is C, B.

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Detailed Solution

D(+) glucose[+] =(+52)+D(+) fructose[+92] =(sucrose hydrolysis)

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For 'invert sugar', the correct statement(s) is/are) : [Given specific rotations of (+}·sucrose (+)-maltose, L-(-)-glucose and L-(+)-fructose in aqueous solution are +66°, +140°, -52° and +92° respectively.]