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Q.

For isothermal expansion of an ideal gas into vacuum, among the following how many are zero 

ΔE,ΔH,ΔT,Q,Pext,ΔSsys,ΔSsur,ΔStotal,ΔGsys

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a

8

b

6

c

9

d

5

answer is A.

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Detailed Solution

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For isothermal (T = constant) expansion of an ideal gas into vacuum ; w = 0 since pex = 0. Also, Joule determined experimentally that q = 0; therefore, ∆U = 0

ΔE=ΔH=ΔT=q=pαt=ΔSsur=0

ΔSsys=ΔStotal=+ve,ΔGsysve

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