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Q.

For one mole of an ideal gas , which of these statements must be true ?
(i)     U and  H  each depends only on temperature
(ii)    Compressibility factor  z is not equal to 1
(iii)   Cp.mCv.m=R
(iv)   dU=CVdT for any process

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a

(ii),(iii) and (iv)

b

(iii) and (iv)

c

(i),(iii) and (iv)

d

(i),and(iii) 

answer is A.

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Detailed Solution

Internal energy(U) of an ideal gas depends only on temperature(T), neither on volume(V) nor the pressure(P)

The heat absorbed by gas is equal to its internal heat engine, when ideal gas undergoes process involving only P-V work.

Therefore, for an ideal gas,

Cv=dV/dT du=CVdT

For an ideal gas, Z=1

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