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Q.

For reaction a AxP, when [A] = 2.2 mM, the rate was found to be 2.4 mMs1. On reducing concentration of A to half, the rate changes to 0.6 mMs1. The order of reaction with respect to A is 

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a

1.5

b

2.0

c

2.5

d

3.0

answer is B.

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Detailed Solution

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aAxP

Rate of reaction =[A]a

Order of reaction = a

[A]1=2.2 mMr1=2.4 mM s1 ...... (i)

[A]2=2.2/2 mM, r2=0.6 mM s1 or, 2.44.....(ii)

On reducing the concentration of A to half, the rate of reaction is decreased by four times. 

Rate of reaction =[A]2

Order of reaction = 2.

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