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Q.

For reaction MnO2+4HClMnCl2+2H2O+Cl2(g)

261 gm MnO2 is mixed with 448 litres of HCl gas at 273C and 1 atm pressure to produce product [NA= 6×1023; Atomic mass of  Mn=55,Cl=35.5]

Select correct statement(s).

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a

Moles of excess reactant left is 0.5 moles.

 

b

If % yield of reaction is 50%, then mass of MnCl2 obtained will be 315.

c

Chlorine gas produced contains 15×1023 molecules.

 

d

MnO2 is limiting reagent.

answer is B, C.

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Detailed Solution

MnO2+4HClMnCl2+2H2O+Cl2(g)

n=26187    22422.4=3    =10

0.5 mole (L.R)  104×NA

Hence, options B and C are correct.

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