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Q.

For real gases Vander Waal's equation is written as 

p+an2V2(Vnb)=nRT

where 'a' and 'b' are Vander Waal's constants. Two sets of gases are 

O2,CO2,H2  and He   (II) CH4,O2 and H2

The gases given in set-I increasing order of 'b' and gases given in set-ll in decreasing order of ·a', are arranged below. Select the correct order from the following 

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a

 (I) He<H2<CO2<O2 (II) CH4>H2>O2

b

 (1) O2<He<H2<CO2 (II) H2>O2>CH4

c

 (I) H2<He<O2<CO2 (II) CH4>O2>H2

d

 (I) H2<O2<He<CO2 (II) O2>CH4>H2

answer is C.

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Detailed Solution

Molar mass i. 'a' increases 

Size of molecule i, 'b' increase

 b(L/mol)       a bar. .L2/mol2H20.02661    CH42.283He0.0237    O21.378O20.03183    H20.2476CO20.04267    

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