Q.

For reversible Galvanic cell, thermodynamic parameters are given as : 

(ΔG)T.P=ΔHTΔS, (ΔG)T.P=nFEcell, ΔS=nF[dEcelldT]P, Wusefull=(ΔG)T.P

for  given  cell  Pt   |H2|  HCl  |AgCl|, Ag, variation of e.m.f. of the cell with temperature is given as Ecell(in  volt)=0.4[2×106(T)2] (T = temperature in Kelvin). (Use : 1F = 96500 C)

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