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Q.

For the cell prepared from electrode 
A:Cr2O72Cr3+,Ered =+1.33V and electrode
B:Fe3+Fe2+,Ered =0.77V Which of the following stament is correct? 

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a

The electrons will flow from B to A when connection is made

b

The e.m.f. of the cell will be 0.56V

c

A will be positive electrode

d

All of the above

answer is D.

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Detailed Solution

The  SRP of B is les than A ,thus electron will flow Fe(B) electrode to Cr(A) electrode.

Fe looses electron so it is negative electrode also Cr will be positve electrode . 

Ecello=ECro- EFeo          = 1.33- 0.77=+0.56V

Hence all statements are correct . 

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