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Q.

for the cell reaction, Cu2+C1,aq+Zn(s)=Zn2+C2,aq+Cu(s) of an electrochemical cell, the change in free energy, ΔG,at a given temperature is a function of 

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a

lnC1

b

lnC2/C1

c

lnC1+C2

d

lnC2

answer is B.

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Detailed Solution

ΔG=nEF
For concentration cell, E=RTnFlnC2C1

In it R, T, n and F are constant 
 So E is based upon lnC2/C1
Now ΔG=nEF=nF×RTnFlnC2/C1
=RTlnC2/C1
At constant temperature  G is based upon  lnC2/C1

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