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Q.

For the cell reaction: Hg2Cl2(s)+2Ag(s)2Hg(l)+2AgCl(s)
Temperature coefficient of cell emf is found to be 0.02 VK -1  Find S0 for cell reactions in kJ mole-1K–1 (Round off your answer to the next higher integer)

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answer is 4.

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Detailed Solution

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ΔS0=nFdEdT=2×96500×0.021000=3.864

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