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Q.

For the depression in freezing point experiment, the correct statement(s) is/are: 

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a

vapour pressure of pure solvent is more than that of solution

b

vapour pressure of pure solvent is less than that of solution

c

only solute molecules solidify at the freezing point

d

only solvent molecules solidify at the freezing point

answer is A, D.

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Detailed Solution

According to Raoult's Law:

At a given temperature, the partial pressure of each component is equal to the product of vapor pressure of the pure component and its mole fraction (x).

p=xp

If a solution starts to freeze, the solvent molecules will solidify, leaving the non volatile to form a more concentrated  solution.

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