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Q.

For the discharge of equal masses of the following ions, the number of electrons required is maximum in the case of

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a

H+

b

Al3+

c

Ag+

d

Cu2+

answer is A.

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Detailed Solution

According o Faraday's law of electrolysis 

Mass of substance deposited(w) =E Xi X  t 96500=M Xi Xt n Xt 

E= equivalent weight 

i= current 

t= time 

M= molecular mass 

n= number of electron required . 

The equation indicates us 

The number of electrons required α number of gram equivalents 

number of gram equivalents = weight Equivalent weight

The substance which has less equivalent weight will be deposited more equivalents for the same mass and required electrons are more. 

EH=1

Ecu=32

EAg = 108

EAl = 9

As the equivalnet weight of H+ is less it required more number of electrons. 

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