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Q.

For the disproportionation reaction,2Cu+cu+cu+2  at 298K. ln K(where K is the equilibrium constant) is x×101M1 . Here ‘X’ is  E0cu+2/cu=0.16V:E0cu+/cu=0.52V;RTF=0.025
 

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answer is 144.

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Detailed Solution

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E0cell=RTnF  lnKcE0cell=E0cu+/cuE0cu+2/cu+=0.520.16=0.36V0.36V=0.025×lnKclnKc=0.360.025=14.4

=144×101

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