Questions  

For the dissociation of PCl5 s into PCI 3 and CI2 , in gaseous phase reaction, if d is the observed vapour density and D the theoretical vapour density with  α as degree of dissociation. Variation of D/d with 'αis given by which graph?

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a
b
c
d
None of these
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detailed solution

Correct option is A

          PCl5(g)PCl3(g)+Cl2(g) t=0;      a            0           0 teq. ;     a-                 van't hoff factor, i=MTMo MT=iMo 2D=2id D=(+-+aa)d Dd=1+α α=Dd-1   If Dd at x-axis and (α) at y-axis  then it is a straight line positive slope and negative intercept.

Where, MT=Theoretical Molar mass, Mo=Observed Molar mass.

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