Q.

For the dissociation: N2O5(g) 2NO2(g) + 12 O2(g). If, M = Molecular mass of N2O5(g) ; D =

vapour density of equilibrium mixture; P° = Initial pressure of N2O5(g). Identify the ‘true’ statements :

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a

Equilibrium pressure can be expressed as 2P°DM

b

Increase in temperature will lower the magnitude of D

c

Equilibrium pressure can be expressed as P°M2D

d

Degree of dissociation can be expressed as (M  2D)3D

answer is A, D.

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Detailed Solution

N2O5(g) 2NO2(g) +12O2(g)

1  α                                2α                          α/2

D = M2 (1  α + 2α + α2) = M2 (1 + 2).......(i)

Peqm = (1 + 2)1 = M2D Peqm = P°M2D

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