Q.

For the electrochemical cell . M/M+//X/X, E(M+/M=0.44V)0 and Ex/x0=0.33V .From the data one can deduce that

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a

M+XM++X(spontaneous )

b

Ecell  for this couple =0.11V

c

Ecell  for this couple =0.77 V

d

M++XM+X (spontaneous) 

answer is B, D.

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Detailed Solution

SRP of M/M>x/xΘ So, X/X/0.33//M+/M/0.44 Ecell 0=0.440.33=0.11VxΘ+Mx+M  spontaneous.   But E0 for given cell =0.11V

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