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Q.

For the electrons of oxygen atom, which of the following statements is correct?

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a

Zefffor an electron in a 2s – orbitals is the same as Zeff for an electron in a 2p - orbitals

b

An electron in the 2s- orbitals has the same energy as an electron in the 2p- orbitals

c

Zefffor an electron in 1s- orbitals is the same as Zeff for an electron in a 2s – orbitals

d

The two electrons present in the 2s- orbitals have spin quantum numbers ms  but of opposite sign

answer is D.

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Detailed Solution

(A)Electrons in 2s and 2p- orbitals have different screening effect. Hence their Zeff     is different  Zeff of 2s- orbitals > Zeff of 2p-orbitals. Therefore, it is not correct

(B) Energy of 2s – orbitals < energy of 2p – orbitals

(C) Zeff  of 1s – orbitals  Zeff of 2s – orbitals. Hence, it is correct

(D)For the two electrons of 2s – orbitals, the value of  ms is +12and12

  Hence, it is correct

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