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Q.

For the equilibrium in gaseous phase in 2 lit flask, we start with 2 moles of  SO2   and 1 mole of   O2 at 3 atm   2SO2(g)+O2(g)   2SO3(g).  When  equilibrium   is attained, Pressure changes to 2.5 atm. Hence equilibrium constant  KC   is

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a

2

b

3

c

4

d

5

answer is C.

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Detailed Solution

 2SO2(g)+O2(g)2SO3(g)
2               1            0
22x          1x       2x
Moles at equilibrium  = 3x
At equilibrium pressure becomes  2.5 atm 
Since pv = n RT
Hence      p  α  n  
Thus  3x3=253,  x=0.5
[SO2]=22x2=0.5M [O2]=1x2=0.25M  ;   (SO3)=2x2=0.5M Kc=[SO3]2[SO2]2[O2]=(0.5)2(0.5)2×0.25=4


 

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