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Q.

For the equilibrium large {A_{(g)}}, rightleftharpoons ,{B_{(g)}}, + ,{C_{(g)}}; Kp = 0.82 atm at 270C. At the same temperature its Kc in mol lit-1 is (R = 0.082 lit atm mol-1 K-1)

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a

0.033

b

3.3

c

1.0

d

0.33

answer is A.

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Detailed Solution

large {A_{(g)}}, rightleftharpoons ,{B_{(g)}}, + ,{C_{(g)}};

Δng = nP (g) -nR (g)

Δng = 2 - 1

Δng = 1

KP = KC (RT)Δn
0.82 = KC (0.0821 ×300)1

large K_C = frac{1}{30}=0.033M
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