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Q.

For the equilibrium reaction N2O42NO2 at certain temperature 20% of reactant is dissociated into 

products . If ‘p’ is total pressure then 

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a

Kp = 6p

b

Kp = 2p

c

p = Kp

d

p = 6Kp

answer is D.

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Detailed Solution

N2O42NO2 1                0  ---initial moles 1-x           2x---moles at equilibrium

total moles at equilibrium = 1 + x

pN2O4=1-x1+xp

pNO2=2x1+xp

Kp = pNO22pN2O4

substituting x = 0.2 and solving 

p = 6 Kp

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