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Q.

For the equilibrium
CO+H2OCO2+H2
The relation between Kp and Kc at 25°C and at 100°C are

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a

Kp=Kc(RT),Kp=Kc

b

Kp=Kc(RT)-1,Kp=Kc

c

Kp=Kc,Kp=Kc

d

Kp=Kc(RT),Kp=Kc(RT)

answer is D.

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Detailed Solution

The effect of pressure depends on the Δng of reaction
Δng=nP(g)-nR(g)
Δng=0, No effoct of prossure.

Δng=+ve, P increases, the reaction takes place in a backward direction or vice-versa.

 Δng=-ve,P increases, the reaction takes place in a forward direction or vice-versa.

For the given reaction,

CO(g)+H2O(g)CO2(g)+H2(g)

Δng=0

So, the equilibrium constant in terms of pressure becomes,

Kp=Kc(RT)n; at 25°C

And

Kp=Kc at 100°C

Thus, option 4 is correct.

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