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Q.

For the equilibrium.

SrCl26H2O(s)SrCl22H2O(s)+4H2O(g)

the equilibrium constant KP=16×1012atm4 at 1C. If one litre of air saturated with water vapour at 1C is exposed to a large quantity of SrCl22H2O(s), what weight of water vapour will be absorbed? Saturated vapour pressure of water at 1C =7.6 torr.

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a

3.25 mg

b

8.5 mg

c

6.4 mg

d

2.3 mg

answer is A.

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Detailed Solution

Here, the pressure on the water molecule,

PH2O4=16×1012

PH2O=2×103atm

Vapor pressure =7.6760=102atm

w=(ΔP)VRT×M=1022×103×10.0821×274×18=6.4mg

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For the equilibrium.SrCl2⋅6H2O(s)⇌SrCl2⋅2H2O(s)+4H2O(g)the equilibrium constant KP=16×10−12atm4 at 1∘C. If one litre of air saturated with water vapour at 1∘C is exposed to a large quantity of SrCl2⋅2H2O(s), what weight of water vapour will be absorbed? Saturated vapour pressure of water at 1∘C =7.6 torr.