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Q.

For the first order reaction : H2O2(aq)H2O(l)+12O2(g)

the half life of reaction is 30 min. If the volume of O2(g) collected at a certain pressure and temperature is 100 ml after a long time from the start of reaction, then what was the volume of O2(g) collected at the same pressure and temperature after 60 min from the start of reaction?

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a

25 ml

b

50 ml

c

75 ml

d

12.5 ml

answer is B.

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Detailed Solution

First order reaction given in the problem is,

H2O2(aq)H2O(l)+12O2(g)

Here,

k×t=lnVVVtln230×60=ln100100VtVt=75mL

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