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Q.

For the first-order reaction Tav (average life), T50 and T75 in the increasing order are :

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a

T50<Tav<T75

b

T50<T75<Tav

c

Tav<T50<T75

d

Tav=T50<T75

answer is A.

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Detailed Solution

The average temperature with respect to rate constant,

Tavg =1K=1.44T1/2

The time taken T50 is half then time taken for T75.

T3/4=2×T1/2

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