Q.

For the following concentration cell, to be  spontaneous Pt H2P1 atm. |HCl|PtH2P2  Which of the following is correct?

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a

P1>P2

b

P1<P2

c

Can’t be predicted

d

P1=P2

answer is C.

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Detailed Solution

The Nernst equation is 

Ecell=Ecello+0.05912log P1P2

For the cell reaction to be spontaneous, Ecell >+ve , which is possible  if P1> P2.

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